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Alcohol Ethoxylates

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Alcohol Ethoxylates
Names
Other names
  • Ethoxylated alcohol
  • Alkyl polyoxyethylene glycol
  • Alkyl PEG ether
Identifiers
ChEBI
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Properties
CH
3
(CH
2
)
m
(OCH
2
CH
2
)
n
OH
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Alcohol ethoxylates, also known as ethoxylated alcohols or alkyl PEG ethers, are a class of chemical compounds produced by the ethoxylation of fatty alcohols.[1][2][3] They are commonly used as nonionic surfactants and consist of a hydrophobic alkyl chain derived from the fatty alcohol and a hydrophilic poly(ethylene oxide) chain formed from repeated ethylene oxide units. Alcohol ethoxylates can be represented by the general chemical formula CH
3
(CH
2
)
m
(OC
2
H
4
)
n
OH
. In addition to their surfactant applications, alcohol ethoxylates are also used as humectants, skin-conditioning agents, and solvents in cosmetic formulations.[3]

Nomenclature

Alcohol ethoxylates used in cosmetics are often named based on the fatty alcohol they are derived from and the number of ethylene oxide units in their hydrophilic tails.[3] For example, the name steareth-10 is given to the ethoxylated alcohol derived from stearyl alcohol appended with an average of 10 ethylene oxide units, i.e. CH
3
(CH
2
)
17
(OC
2
H
4
)
10
OH
.[4][3] The fatty alcohols used for ethoxylation are typically mixtures and naming conventions depend on the average Cn chain length.[1]

For alcohol ethoxylates, chemists often use the shorthand formula CmEn, where m denotes the average number of carbon atoms in the fatty alcohol chain and n denotes the average number of ethylene oxide units in the poly(ethylene oxide) chain.[1]

Synthesis

Alcohol ethoxylates are formed by reacting fatty alcohols with ethylene oxide in the presence of a catalyst, i.e. an ethoxylation reaction.

Properties

Uses

References

  1. 1.0 1.1 1.2 Tadros, Tharwat F. (2014-12-31). An Introduction to Surfactants. DE GRUYTER. p. 12. doi:10.1515/9783110312133. ISBN 978-3-11-031212-6. Search this book on
  2. Nace, Vaughn (2017-10-19). Nace, Vaughn M., ed. Nonionic Surfactants: Polyoxyalkylene Block Copolymers (1 ed.). CRC Press. doi:10.1201/9780203745656. ISBN 978-0-203-74565-6. Search this book on
  3. 3.0 3.1 3.2 3.3 Fiume, Monice M.; Heldreth, Bart; Bergfeld, Wilma F.; Belsito, Donald V.; Hill, Ronald A.; Klaassen, Curtis D.; Liebler, Daniel; Marks, James G.; Shank, Ronald C.; Slaga, Thomas J.; Snyder, Paul W.; Andersen, F. Alan (2012). "Safety Assessment of Alkyl PEG Ethers as Used in Cosmetics". International Journal of Toxicology. 31 (5_suppl): 169S–244S. doi:10.1177/1091581812444141. ISSN 1091-5818. PMID 23064774.
  4. "CIR Portal Ingredient Status Report". cir-reports.cir-safety.org. Retrieved 2025-12-21.


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