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List of ions

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This is a list of simple ions, indexed according to the periodic table. Simple ions in the list are defined as โ‰ค5 non-H atoms.

Alkali metals and alkaline earth metals

Elements Ions Colors Examples Properties
H H+ colorless HClO4
Hโˆ’ colorless NaH Hโˆ’ + H2O = OHโˆ’ + H2(g)
Li Liโˆ’ Li+(calix[4]pyrrole)Liโˆ’[1]
Li+ colorless LiNO3 (abbr. for [Li(H2O)4]+ or [Li(H2O)6]+)
Flame test of Li+ is crimson red
Na Na+ colorless NaCl (abbr. for [Na(H2O)n]+, n=4 - 6[2]๏ผ‰
Flame test of Na+ is yellow
K K+ colorless KI (abbr. for [K(H2O)n]+, n=6, 7,[3] 8[4])
Flame test of K+ is lilac
Rb Rb+ colorless RbCl
Cs Cs+ colorless CsCl
Be Be2+ colorless BeSO4 very toxic
BeF42โˆ’ colorless (NH4)2BeF4
BeCl42โˆ’ colorless Cs2BeCl4 unstable
[Be(OH)4]2โˆ’ colorless Na2[Be(OH)4] [Be(OH)4]2โˆ’ + 4 H+ = Be(OH)2(s) + 2 H2O
Mg Mg2+ colorless MgCl2
Ca Ca2+ colorless CaCl2
Sr Sr2+ colorless SrCl2
Ba Ba2+ colorless BaCl2 toxic
Ba2+ + CO32โˆ’ = BaCO3
Ba2+ + SO42โˆ’ = BaSO4

Group 3 elements

Elements Ions Colors Examples Properties
Sc Sc3+ colorless Sc(NO3)3
[Sc(OH)6]3โˆ’ colorless K3[Sc(OH)6]
Y Y3+ colorless
La La3+ colorless
Ce Ce3+ colorless[5] Ce(NO3)3
Ce4+ orange-yellow[6] Ce(SO4)2
Pr Pr3+ green[5] Pr(NO3)3
Th Th4+ colorless Th(NO3)4 Th4+ + 4 OHโˆ’ = Th(OH)4(s)
U U3+ brown-red UCl3
U4+ green
UO2+ unstable
UO22+ yellow[7] UO2(NO3)2

Group 4 - 7 elements

Elements Ions Colors Examples Properties
Ti Ti3+ violet Ti2(SO4)3 (abbr. for [Ti(H2O)6]3+)
reductant
TiO2+ (abbr. for [TiO(H2O)5]2+)
TiF62โˆ’ colorless K2TiF6
TiCl62โˆ’ yellow Cs2TiCl6
TiBr62โˆ’ red
Zr Zr4+ colorless Zr(NO3)4.5H2O (abbr. for [Zr(H2O)8]4+)
ZrO2+ colorless ZrO(NO3)2 (abbr. for [Zr4(OH)8(H2O)16]8+[4])
Hf Hf4+ colorless (abbr. for [Hf(H2O)8]4+)
Cr Cr2+ light blue CrSO4 (abbr. for [Cr(H2O)6]2+)
reductant
Cr3+ grayish green Cr(NO3)3 (abbr. for [Cr(H2O)6]3+)
CrO42โˆ’ orange K2CrO4
Cr2O72โˆ’ yellow K2Cr2O7

Group 8 - 10 elements

Elements Ions Colors Examples Properties
Fe [Fe(CO)4]2โˆ’
Fe2+ light green FeSO4.7H2O Fe2+ + 2 OHโˆ’ = Fe(OH)2
Fe2+ + CO32โˆ’ = FeCO3
Fe3+ pale purple NH4Fe(SO4)2
[Fe(phen)3]2+ dark red
[Fe(phen)3]3+ light blue
FeO42โˆ’ purple K2FeO4 strong oxidant
Co [Co(CO)4]โˆ’ K[Co(CO)4] oxidized in air
Co2+ pink Co(NO3)2.6H2O
[Co(NH3)6]2+
[Co(NH3)6]3+ orange [Co(NH3)6](NO3)3 stable
Ni Ni2+ green Ni(NO3)2 Ni2+ + 2 OHโˆ’ = Ni(OH)2
[Ni(NH3)6]2+ blue
[NiF4]2โˆ’
[NiCl4]2โˆ’
[NiBr4]2โˆ’ [Ph4P]2[NiBr4][8]
[NiI4]2โˆ’ red
[Ni(CN)4]2โˆ’ yellow K2[Ni(CN)4]

Group 11 - 12 elements

Elements Ions Colors Examples Properties
Cu Cu2+ blue Cu(NO3)2 (abbr. for [Cu(H2O)4]2+ or [Cu(H2O)6]2+[4]
[Cu(NH3)4]2+ dark blue [Cu(NH3)4](NO3)2 decomposes by acids
Ag Ag+ colorless AgNO3 2 Ag+ + 2 OHโˆ’ = Ag2O + H2O (r.t.)
[Ag(NH3)2]+[9] colorless [Ag(NH3)2]OH decomposes by acids
AgCl2โˆ’ colorless AgCl in conc. Clโˆ’ solution
[Ag(CN)2]โˆ’ colorless toxic
Au AuCl4โˆ’ yellow NaAuCl4
AuBr4โˆ’ purple KAuBr4
Zn Zn2+ colorless Zn(NO3)2 white in silicate garden
[Zn(NH3)4]2+ colorless [Zn(NH3)4](OH)2
[Zn(OH)4]2โˆ’ colorless
[Zn(CN)4]2โˆ’ colorless K2[Zn(CN)4] toxic
Cd Cd2+ colorless Cd(NO3)2
Hg Hg22+ colorless Hg2(NO3)2 (abbr. for [Hg2(H2O)6]2+[4])
Hg2+ colorless Hg(NO3)2 (abbr. for [Hg(H2O)6]2+
very toxic

Boron group and carbon group

Elements Ions Colors Examples Properties
B BH4โˆ’ colorless NaBH4 strong reductant
BF4โˆ’ colorless HBF4 non-coordinating anion
Al Al3+ colorless Al(NO3)3
C CO32โˆ’ colorless Na2CO3
HCO3โˆ’ colorless NaHCO3
CNโˆ’ colorless KCN very toxic
CNโˆ’ + H+ = HCN
Si SiO32โˆ’ colorless Na2SiO3 SiO32โˆ’ + 2 H+ = H2SiO3
SiF62โˆ’ colorless Na2[SiF6]
Ge GeO32โˆ’ colorless Na2GeO3
Sn Sn2+ colorless SnCl2 Reductant
exists in acidic solution
Pb Pb2+ colorless Pb(NO3)2 Pb2+ + 2 Iโˆ’ = PbI2(s)

Pnictogens and chalcogens

Elements Ions Colors Examples Properties
N NH4+ colorless NH4Cl
N3โˆ’ Na3N reacts with water
NH2โˆ’ NaNH2 reacts with water
N3โˆ’ NaN3 very toxic
NO2โˆ’ NaNO2 toxic
NO3โˆ’ colorless KNO3 oxidant
P PH4+ colorless PH4I dec. in water
PO43โˆ’ colorless Na3PO4
P2O74โˆ’ colorless Na4P2O7
PF6โˆ’ colorless KPF6 non-coordinating anion
O OHโˆ’ colorless NaOH corrosive
O22โˆ’ Na2O2 ionic peroxides react with water
O2โˆ’ Al2O3
S S2โˆ’ colorless Na2S
S22โˆ’ Na2S2 S22โˆ’ + 2 H+ = H2S + S
S2O32โˆ’ colorless Na2S2O3 S2O32โˆ’ + 2H+ = SO2 + S + H2O
SO32โˆ’ colorless Na2SO3 SO32โˆ’ + 2 H+ = H2O + SO2
SO42โˆ’ colorless K2SO4

Halogens and noble gases

Elements Ions Colors Examples Properties
F Fโˆ’ colorless CsF
HF2โˆ’ colorless KHF2 unstable towards heat
Cl Clโˆ’ colorless NaCl Clโˆ’ + Ag+ = AgCl
OClโˆ’ NaOCl strong oxidant
ClO2โˆ’ NaClO2
ClO3โˆ’ colorless KClO3
ClO4โˆ’ colorless KClO4
Br Brโˆ’ colorless KBr
BrO3โˆ’ colorless KBrO3 oxidant
I I2+ blue
I3+ red-brown
Iโˆ’ colorless KI reductant
2 Iโˆ’ + Cl2 = 2 Clโˆ’ + I2
2 Iโˆ’ + Br2 = 2 Brโˆ’ + I2
I3โˆ’ CsI3
IO3โˆ’ colorless KIO3
ICl4โˆ’ KICl4
IO4โˆ’ colorless KIO4
He HHe+ extremely strong acid
Ar HAr+ found in space
Xe XeO64โˆ’ Na4XeO6 strong oxidant
HXeO4โˆ’ CsHXeO4

References

  1. โ†‘ Wei Chen, Zhi-Ru Li, Di Wu, et al. Nonlinear Optical Properties of Alkalides Li+(calix[4]pyrrole)Mโˆ’ (M = Li, Na, and K): Alkali Anion Atomic Number Dependence. J. Am. Chem. Soc., 2006, 128 (4), pp 1072โ€“1073
  2. โ†‘ Lincoln, S.F.; Richens, D.T.; Sykes, A.G. (2004). "Comprehensive Coordination Chemistry II": 515. doi:10.1016/B0-08-043748-6/01055-0. ISBN 978-0-08-043748-4. |chapter= ignored (help))
  3. โ†‘ Lincoln, S. F.; Richens, D. T. and Sykes, A. G. "Metal Aqua Ions" in J. A. McCleverty and T. J. Meyer (eds.) Comprehensive Coordination Chemistry II, Vol. 1, pp. 515โ€“555, ISBN 978-0-08-043748-4 Search this book on ..
  4. โ†‘ 4.0 4.1 4.2 4.3 Hydrated metal ions in aqueous solution: How regular are their structures. Pure Appl. Chem., 82 (10): 1901-1917, 2010
  5. โ†‘ 5.0 5.1 Cotton, Simon (2006). Lanthanide and Actinide Chemistry. John Wiley & Sons Ltd
  6. โ†‘ Sroor, Farid M.A.; Edelmann, Frank T. (2012). "Lanthanides: Tetravalent Inorganic". Encyclopedia of Inorganic and Bioinorganic Chemistry. ISBN 9781119951438 Search this book on .. doi:10.1002/9781119951438.eibc2033.
  7. โ†‘ Seaborg, Glenn T. (1968). "Uranium". The Encyclopedia of the Chemical Elements. Skokie, Illinois: Reinhold Book Corporation. pp. 773โ€“786. LCCCN 68-29938
  8. โ†‘ Goodgame, D. M. L.; Goodgame, M.; Cotton, F. A. (October 1961). "Electronic Spectra of Some Tetrahedral Nickel(II) Complexes". Journal of the American Chemical Society. 83 (20): 4161โ€“4167. doi:10.1021/ja01481a014.
  9. โ†‘ Nilsson, K. B., Persson, I., Kessler, V. G., "Coordination Chemistry of the Solvated AgI and AuI Ions in Liquid and Aqueous Ammonia, Trialkyl and Triphenyl Phosphite, and Tri-n-butylphosphine Solutions", Inorganic Chemistry 2006, volume 45, pp. 6912. doi:10.1021/ic060175v


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