Quantum rate theory
In physical chemistry, quantum rate theory is a method of calculating the dynamics of electron transfer between different quantum states.[1][2] It uses the ratio of the conductance quantum and the quantum capacitance to derive a general equation for the rate of chemical reactions[3] and the rate of electron transfer between states as a particular case. For example, note how the rate of electron transfer in quantum electrochemistry[4][5][6][7] is calculated using the quantum rate approach. Note that the method encompasses Marcus theory of electron transfer as a particular setting of this theory.
See also
- Marcus theory
- Transition State Theory
References
- ↑ Bueno, P. R. (2018). The Nanoscale Electrochemistry of Molecular Contacts. Springer. Search this book on
- ↑ Bueno, P. R. (2020). "Electron transfer and conductance quantum". Physical Chemistry Chemical Physics. 22 (45): 26109–26112. doi:10.1039/D0CP04522E. PMID 33185207 Check
|pmid=value (help). Unknown parameter|s2cid=ignored (help) - ↑ Pollak, Eli; Talkner, Peter (2005). "Reaction rate theory: What it was, where is it today, and where is it going?". Chaos. 15 (2): 026116. doi:10.1063/1.1858782. PMID 16035918.
- ↑ Bueno, P. R. (2018). The Nanoscale Electrochemistry of Molecular Contacts. Springer. Search this book on
- ↑ Bueno, P. R. (2020). "Electron transfer and conductance quantum". Physical Chemistry Chemical Physics. 22 (45): 26109–26112. doi:10.1039/D0CP04522E. PMID 33185207 Check
|pmid=value (help). Unknown parameter|s2cid=ignored (help) - ↑ Alarcon, E. V. G.; Santos, A.; Bueno, P. R. (2021). "Perspective on quantum electrochemistry. A simple method for measuring the electron transfer rate constant". Electrochimica Acta. 398: 139219. doi:10.1016/j.electacta.2021.139219. Unknown parameter
|s2cid=ignored (help) - ↑ Sanchez, Y. P.; Santos, A.; Bueno, P. R. (2022). "Quantum Mechanical Meaning of the Charge Transfer Resistance". Journal of Physical Chemistry C. 126 (6): 3151–3162. doi:10.1021/acs.jpcc.1c07801. Unknown parameter
|s2cid=ignored (help)
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